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The voltage rating is simply the voltage the cable will safely withstand... not relevent in this application.
When a cd-rom is attached to a hard drive ribbon, the hard drive access speed will drop to that of the cd-rom i.e. UDMA 2 at best. if you have a fast system and fast HD's, you stand to loose a lot of performance and your HD's speed (UDMA100 or whatever) will be wasted.
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