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normally, intel puts a little square of black greasy stuff on the bottom of their heatsink/fans. it is only good for 1 squeeze, just like any good tube of gook should have on the label. If the square was there, you will need to peel it off (it will have a foil backing that needs to come off), and clean the heatsink with acetone or alcohol. then apply some thermal goop, but i like to put it on the heatsink itself, not on the chip. (that will probably cause replies to the contrary!)
there are a couple of good reasons to reapply the goop, but the main one is that it can get a little thicker over time, and if you reuse it, it can cause air bubbles in between the chip and heatsink, and air does not conduct heat. so if you take the heatsink off, reapply the goop. Unless you are overclocking or having heat trouble, you probably won't get any performance increase, but your computer will continue to function as opposed to burning up.
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