Nero has a check box when burning, something like "Verify files after burn", check it and it will do it for you:
Get it here
Or free, through other sources on 't web, leave that choice to you...
You could also create a md5sum for each file and check the md5sum of your files on the disk against the original md5sums. Basically, using an algorithm it creates a string of 24 (i think) alphanumeric characters, i.e slim chance of it going wrong,
very slim.
Windows NT, for some reason, dont come with md5sum built into the DOS shell. You will have to download a 'lil .exe to your /windows/system32 dir and the run it. Google for more info.
md5sum'n is overkill though, im sure nero's checking will use some simular hashing algortihm for checking, just though i would give you two options.
Also (i think) alcohol 120% has checking for buring, and it also lets you mount .iso files, .bin's etc without having to burn em - faster and cheaper...google it.
Hope this helps,
Jammin