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if you are looking for POP and SMTP server address , then I have to say you don't need it ! when you are settingup the account you have to mention that it is a HTTP mail (so far Outlook only allows HTTP mail form only Hotmail account, but that is beside the point) ,, as long as you say HTTP mail it will automatically set it for Hotmail.
cheers
p.s it does not matter if you are behind a firewall or not, but if you are in a organization where they use Porxy for internet Access then the chances are that pop email address will not work either.
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