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I'm pretty sure that Outlook 2003 can't use the same .pst file that Outlook 2000 used without importing the data so Outlook 2003 can put it into a format it can use.
It's worth a shot. In Outlook, go to File>Import and Export, choose "Import from another program or file," then "Personal Folder file (pst), browse to the location of the pst file you want it to use, continue stepping through the wizard and see if that gets your data into Outlook 2003.
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